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Beilstein J. Org. Chem. 2014, 10, 1802–1807, doi:10.3762/bjoc.10.189
Graphical Abstract
Scheme 1: An anomalous outcome with benzylamine as organic base.
Scheme 2: Transformation of vicinal haloamines by the use of organic amines.
Figure 1: ORTEP diagram of compound 5o.
Scheme 3: Ring-opening of aziridine 6.
Scheme 4: Proposed mechanism.
Beilstein J. Org. Chem. 2014, 10, 746–751, doi:10.3762/bjoc.10.69
Scheme 1: Previous work for (R)-(1-amino-3-methylbutyl)boronic acid synthesis.
Scheme 2: Synthesis of (R)-4 and Velcade.
Figure 1: ORTEP diagram of (S,S,R)-3a (left, most of the hydrogen atoms were omitted except the one on the ch...
Scheme 3: Synthesis of phosphinylimines and their borylation products.
Beilstein J. Org. Chem. 2014, 10, 653–659, doi:10.3762/bjoc.10.57
Figure 1: Typical sulfinyl (a), phosphonyl aldimines (b) and phosphinyl imino esters (c).
Scheme 1: Synthesis of α-imino ester by rearrangement.
Scheme 2: Cleavage of the chiral auxiliary.